Sélection de Publications Scientifiques
2024
Out-of-Equilibrium Mechanical Disruption of β-Amyloid-Like Fibers using Light-Driven Molecular Motors
Daou, D.; Zarate, Y.; Maaloum, M.; Collin, D.; Fleith, G.; Constantin, D.; Moulin, E.; Giuseppone, N.
Adv. Mater. 2024, 36, 2311293.
Scalable Approach to Molecular Motor-Polymer Conjugates for Light-Driven Artificial Muscles
Yao, X.; Vishnu, J. A.; Lupfer, C.; Hoenders, D.; Skarsetz, O.; Chen, W.; Dattler, D.; Perrot, A.; Wang, W.; Gao, C.; Giuseppone N.; Schmid, F.; Walther, A.
Adv. Mater. 2024, 36, 2403514.
Front Cover
Editors' Choice
Driving Supramolecular Systems Uphill with Artificial Molecular Motors
Giuseppone, N.
Solvay Conference Proceeding "Chemistry Challenges of the 21st century", January 2024, 79-86
Molecular Actuation of a Bistable Liquid-Crystalline [c2]Daisy Chain Rotaxane
Carmona-Vargas, C.; Faour, L.; Tokunaga, S.; Constantin, D.; Fleith, G.; Moulin, E.; Giuseppone, N.
ChemistryEurope 2024, 2, e202300069.
Front Cover
2023 - 2021
Bending Actuation of Hydrogels through Rotation of Light-Driven Molecular Motors
Perrot, A.; Wang, W.; Buhler, E.; Moulin, E.; Giuseppone, N.
Angew. Chem. Int. Ed. 2023, 62, e202300263.
Front Cover
Daisy chain architectures: from discrete molecular entities to polymer materials
Moulin, E.; Carmona-Vargas, C.; Giuseppone, N.
Chem. Soc. Rev. 2023, 52, 7333-7358.
A light-driven molecular whirligig.
Gao, C., Vargas Jentzsch, A., Moulin, E., Giuseppone. N.
J. Am. Chem. Soc. 2022, 144, 22, 9845–9852, DOI: 10.1021/jacs.2c02547
Light-driven molecular motors boost the selective transport of alkali ions through phospholipid bilayers.
Wang, W.-Z., Huang, L.-B., Zheng, S.-P. Moulin, E., Gavat, O., Barboiu, M., Giuseppone, N.
J. Am. Chem. Soc., 2021, 143, 15653-15660.
Extraction of Macroscopic Mechanical Work from Stimuli-Responsive Materials.
Perrot, A., Moulin, E., Giuseppone, N.
Trends in Chemistry, 2021, 11, 926-942.
Supramolecular Polymerization of Triarylamine-based Macrocycles into Electroactive Nanotubes.
Picini, F., Schneider, S., Gavat, O., Vargas Jentzsch, A., Tan, J., Maaloum, M., Strub, J.-M., Tokunaga, S., Lehn, J.-M., Moulin, E., Giuseppone, N.
J. Am. Chem. Soc. 2021, 143, 6498-6504.
Optoregulated force application to cellular receptors using molecular motors.
Zheng, Y., Han, M.K.L., Zhao, R., Blass, J., Zhang, J., Zhou, D.W., Colard-Itté, J.-R., Dattler, D., Hoth, M., Garcia, A.J., Bennewitz, R., Giuseppone, N., del Campo, A.
Nature Comm. 2021, 12, 3580.
Template-Directed Synthesis of Redox-Active [c3]Daisy Chain Rotaxanes.
Carmona-Vargas, C., Giuseppone N.
Chem 2021, 7, 11-13.
Spatially Addressed Supramolecular Nanowires: A Full Structural Characterization by GIWAXS.
Galerne, M., Heinrich, B., Hemmerle, A., Fontaine, P., Giuseppone, N., Kékicheff, P.,
ACS Appl. Polym. Mat. 2021, 3, 661-670.
Modulation of the Molecular Structure of Tri-aryl Amine Fibrils in Hybrid Poly[vinyl chloride] Gel/Organogel Systems
Talebpour, P., Heinrich, B., Gavat, O., Carvalho, A., Moulin, E., Giuseppone, N., Guenet, J.-M.,
Macromolecules 2021, 54, 80104-8111.
Design of Stimuli-Responsive Dynamic Covalent Delivery Systems for Volatile Compounds (Part 2): Fragrance-Releasing Cleavable Surfactants in Functional Perfumery Applications.
Tchakalova, V., Lutz, E., Lemboley, S., Moulin, E., Benczédi, D., Giuseppone, N., Herrmann, A.,
Chem. Eur. J. 2021, 27, 13468-13476.
Design of Stimuli-Responsive Dynamic Covalent Delivery Systems for Volatile Compounds (Part 1): Controlled Hydrolysis of Micellar Amphiphilic Imines in Water.
Lutz, E., Moulin, E., Tchakalova, V., Benczédi, D., Herrmann, A., Giuseppone, N.,
Chem. Eur. J. 2021, 27, 13457-13467.
2020 - 2018
From molecular machines to stimuli-responsive materials
Moulin, E. ; Faour, L. ; Carmona-Vargas, C. ; Giuseppone, N.
Adv. Mater. 2020, DOI: 10.1002/adma.201906036
Video Abstract
Design of Collective Motions from Synthetic Molecular Switches, Rotors, and Motors
Dattler, D. ; Fuks, G. ; Heiser, J. ; Moulin, E. ; Perrot, A. ; Yao, X. ; Giuseppone, N.
Chem. Rev. 2020, 120, 310-443.
Front Cover
Self-Assembly of Supramolecular Polymers of N-Centered Triarylamine Trisamides in the Light of Circular Dichroism: Reaching Consensus between Electrons and Nuclei
Koenis, M. A. J. ; Osypenko, A. ; Fuks, G. ; Giuseppone, N. ; Nicu, V. P. ; Visscher, L. ; Buma, W. J.
J. Am. Chem. Soc. 2020, 142, 1020-1028.
Triarylamine-based Supramolecular Polymers: Structures, Dynamics, Functions
Moulin, E.; Armao IV, J. J.; Giuseppone, N.
Acc. Chem. Res. 2019, 52, 975-983.
Front Cover
Covalently trapped triarylamine-based supramolecular polymers
Liang, T. ; Collin, D. ; Galerne, M. ; Fuks, G. ; Vargas Jentzsch, A. ; Maaloum, M. ; Carvalho, A. ; Giuseppone, N. ; Moulin, E.
Chem. Eur. J. 2019, 25, 14341-14348.
Temperature Control of Sequential Nucleation‐Growth Mechanisms in Hierarchical Supramolecular Polymers
Osypenko, A. ; Moulin, E. ; Gavat, O. ; Fuks, G. ; Maaloum, M. ; Koenis, M. A. J. ; Buma, W. J. ; Giuseppone, N.
Chem. Eur. J. 2019, 25, 13008-13016.
Hot Paper
Unsymmetric bistable [c2]daisy chain rotaxanes which combine two types of electroactive stoppers
Wolf, A.; Cid, J.-J.; Moulin, E.; Niess, F.; Du, G.; Goujon, A.; Busseron, E.; Ruff, A.; Ludwigs, S.; Giuseppone, N.
Eur. J. Org. Chem. 2019, 3421-3432.
Invited contribution for the special isse "50 years of rotaxanes" edited by J.-P. Sauvage.
Very Important Paper. Feature Cover.
Mechanical behaviour of contractile gels based on light-driven molecular motors
Colard-Itté, J.-R.; Li, Q.; Collin, D.; Mariani, G.; Fuks, G.; Moulin, E.; Buhler, E.; Giuseppone, N.
Nanoscale 2019, 11, 5197-5202.
[c2]daisy chain rotaxanes as molecular muscles
Goujon, A.; Moulin, E.; Fuks, G.; Giuseppone, N.
CCS Chemistry 2019, 1, 83-96.
Supramolecular Electropolymerization
Ellis, T. K.; Galerne, M.; Armao IV, J. J.; Osypenko, A.; Martel, D.; Maaloum, M.; Fuks, G.; Gavat, O.; Moulin, E.; Giuseppone, N.
Angew. Chem. Int. Ed. 2018, 57, 15749-15753.
Hot Paper
3D supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules
Gavat, O.; Nguyet Trinh, T. M.; Moulin, E.; Ellis, T.; Maaloum, M.; Buhler, E.; Fleith, G.; Nierengarten, J.-F.; Giuseppone, N.
Chem. Commun. 2018, 54, 7657-7660.
Autopoietic Behavior of Dynamic Covalent Amphiphiles
Nguyen, R. ; Jouault, N. ; Zanirati, S. ; Rawiso, M. ; Allouche, L. ; Buhler, E. ; Giuseppone, N.
Chem. Eur. J. 2018, 24, 17125-17137.
2017 - 2015
| Dual-light control of nanomachines that integrate motor and modulator subunits |
| Bistable [c2] Daisy Chain Rotaxanes as Reversible Muscle-like Actuators in Mechanically Active Gels |
| Controlled Sol-gel Transitions by Actuating Molecular Machine based Supramolecular Polymers |
| Integration of molecular machines into supramolecular materials: actuation between equilibrium polymers and crystal-like gels |
| Columnar Self-Assemblies of Triarylamines as Scaffolds for Artificial Biomimetic Channels for Ion and for Water Transport |
| Anisotropic Self-Assembly of Supramolecular Polymers and Plasmonic Nanoparticles at the Liquid–Liquid Interface |
| Existence of Two‐Dimensional Physical Gels even at Zero Surface Pressure at the Air/Water Interface: Rheology of Self‐Assembled Domains of Small Molecules |
| Thermodynamic Selection of Supramolecular Nanomaterials from Dynamic Peptide Librairies |
| Design of Highly Stable Echogenic Microbubbles through Controlled Assembly of Their Hydrophobin Shell |
| Long-Range Energy Transport via Plasmonic Propagation in a Supramolecular Organic Waveguide |
| Supramolecular Organic Nanowires as Plasmonic Interconnects |
| Self-Assembly of Supramolecular Triarylamine Nanowires in Mesoporous Silica and Biocompatible Electrodes Thereof |
| Hierarchical Self-Assembly of Supramolecular Muscle-like Fibers |
| Light Scattering Strategy for the Investigation of Time-evolving Heterogeneous Supramolecular Self-Assemblies |
| Hydrogen-Bonded Multifunctional Supramolecular Copolymers in Water |
| Recruitment and Immobilization of a Fluorinated Biomarker Across an Interfacial Phospholipid Film using a Fluorocarbon Gas |
| The evolution of spatial ordering of oil drops fast spreading on a water surface |
| Macroscopic contraction of a gel induced by the integrated motion of light-driven molecular motors |
| Light-Controlled Morphologies of Self-Assembled Triarylamine-Fullerene Conjugates |
| pH and light-controlled self-assembly of bistable [c2] daisy chain rotaxanes |
| Control over Nanostructures and Associated Mesomorphic Properties of Doped Self-Assembled Triarylamine Liquid Crystals |
| Self-assembled Supramolecular Materials in Organic Electronics |
2014 - 2012
| Supramolecular Self-Assembly and Radical Kinetics in Conducting Self-Replicating Nanowires |
| Atomic force microscopy study of DNA flexibility on short length scales: smooth bending versus kinking |
| Healable supramolecular polymers as organic metals |
| Reversible Native Chemical Ligation: a Facile Access to Dynamic Covalent Peptides |
| DNA flexibility on short length scales probed by atomic force microscopy Mazur, A. K. ; Maaloum, M. Phys. Rev. Lett. 2014, 112, 068104. |
| Chiral mechanical bonds: A move in the right direction Moulin, E. ; Giuseppone, N. Nature Nanotech. 2014, 9, 331–332 |
| Core–shell inversion by pH modulation in dynamic covalent micelles Nguyen, R. ; Jouault, N. ; Zanirati, S. ; Rawiso, M. ; Allouche, L. ; Fuks, G. ; Buhler, E. ; Giuseppone, N. Soft Matter 2014, 10, 3926-3937 |
| Experimental and theoretical methods for the analyses of dynamic combinatorial libraries Misuraca, M.-C. ; Moulin, E. ; Ruff, Y. ; Giuseppone, N. New J. Chem. 2014, 38, 3336-3349. |
| Supramolecular self-assemblies as functional nanomaterials Busseron, E. ; Ruff, Y. ; Moulin, E. ; Giuseppone, N. Nanoscale 2013, 5, 7098-7140. |
| Behavior of an Adsorbed Phospholipid Monolayer Submitted to Prolonged Periodical Surface Density Variations Nguyen, P. N. ; Waton, G. ; Vandamme, T. ; Krafft, M.-P. Angew. Chem. Int. Ed. 2013, 52, 6404-6408. |
| Advances in Supramolecular Electronics – From Randomly Self-assembled Nanowires to Addressable Self-organized Interconnects Moulin, E. ; Cid, J.-J. ; Giuseppone, N. Adv. Mater. 2013, 25, 477-487. |
| Muscle-like Supramolecular Polymers - Integrated Motions from Thousands of Molecular Machines Du, G. ; Moulin, E. ; Jouault, N. ; Buhler, E. ; Giuseppone, N. Angew. Chem. Int. Ed. 2012, 51, 12504-12508. Front Cover Angewandte Highlighted in: Nature Nano. 2013, 8, 9-10. |
| Light-triggered self-assembly of triarylamine-based nanospheres Moulin, E. ; Niess, F. ; Fuks, G. ; Jouault, N. ; Buhler, E. ; Giuseppone, N. Nanoscale 2012, 4, 6748-6751 |
| Light-triggered self-construction of supramolecular organic nanowires as metallic interconnects Faramarzi, V. ; Niess, F. ; Moulin, E. ; Maaloum, M. ; Dayen, J.-F. ; Beaufrand, J.-B. ; Zanettini, S. ; Doudin, B. ; Giuseppone, N. Nature Chem. 2012, 4, 485-490. |
| Toward Self-Constructing Materials : A Systems Chemistry Approach Giuseppone, N. Acc. Chem. Res. 2012, 45, 2178-2188. |
| Dynamic combinatorial chemistry as a tool for the design of functional materials and devices Moulin, E. ; Cormos, G. ; Giuseppone, N. Chem. Soc. Rev. 2012, 41, 1031-1049. |
| Reactions in Dynamic Assemblies Moulin, E. ; Giuseppone, N. Encyclopedia of Supramolecular Chemistry – From molecules to nanomaterials, John Wiley & Sons, Ltd., 2012, 1543-1574. |
| Dynamic Combinatorial Self-Replicating Systems Moulin, E. ; Giuseppone, N. Topics in Current Chemistry, 2012, 322, 87-105. |
| Hierarchical supramolecular structuring and dynamical properties of water soluble polyethylene glycol–perylene self-assemblies Jouault, N. ; Xiang, Y. ; Moulin, E. ; Fuks, G. ; Giuseppone, N. ; Buhler, E. Phys. Chem. Chem. Phys. 2012, 14, 5718-5728. |
2011 - 2004
| Catalytic Accordions Giuseppone, N. ; Lutz, J.-F. Nature 2011, 473, 40-41 |
| SANS, SAXS, and light scattering investigations of pH-responsive dynamic combinatorial mesophases Jouault, N. ; Nguyen, R. ; Rawiso, M. ; Giuseppone, N. ; Buhler, E. Soft Matter 2011, 7, 4787-4800 |
| The Hierarchical Self-Assembly of Charge Nanocarriers : A Highly Cooperative Process Promoted by Visible Light Moulin, E. ; Niess, F. ; Maaloum, M. ; Buhler, E. ; Nyrkova, I. ; Giuseppone, N. Angew. Chem. Int. Ed. 2010, 49, 6974-6978. Frontispiece Cover Angewandte |
| Hierarchical Functional Gradients of pH-Responsive Self-Assembled Monolayers using Dynamic Covalent Chemistry on Surfaces Tauk, L. ; Schröder, A. ; Decher, G. ; Giuseppone, N. Nature Chem. 2009, 1, 649-656. |
| Dynablocks : Structural Modulation of Responsive Combinatorial Self-Assemblies at Mesoscale Nguyen, R. ; Buhler, E. ; Giuseppone, N. Macromolecules 2009, 42, 5913-5915. |
| Dynamic Combinatorial Evolution within Self-Replicating Supramolecular Assemblies Nguyen, R. ; Allouche, L. ; Buhler, E. ; Giuseppone, N. Angew. Chem. Int. Ed. 2009, 48, 1093-1096. Hot Paper Angewandte |
| Electric-Field Triggered Controlled Release of Bioactive Volatiles from Imine-Based Liquid Crystalline Phases Herrmann, A. ; Giuseppone, N. ; Lehn, J.-M. Chem. Eur. J. 2009, 15, 117-124. |
| Self-Duplicating Amplification in a Dynamic Combinatorial Library Xu, S. ; Giuseppone, N. J. Am. Chem. Soc. 2008, 130, 1826-1827. |
| DOSY NMR Experiments as a Tool for the Analysis of Constitutional and Motional Dynamic Processes : Implementation for the Driven Evolution of Dynamic Combinatorial Libraries of Helical Strands Giuseppone, N. ; Schmitt, J.-L. ; Allouche, L. ; Lehn, J.-M. Angew. Chem. Int. E. 2008, 47, 2235-2239. |
| Driven Evolution of a Constitutional Dynamic Library of Molecular Helices towards the Selective Generation of 2x2 Grid-like Arrays under the Pressure of Metal Ion Coordination Giuseppone, N. ; Schmitt, J.-L. ; Lehn, J.-M. J. Am. Chem. Soc. 2006, 128, 16748–16763. |
| Electric-Field Modulation of Component Exchange in Constitutional Dynamic Liquid Crystals Giuseppone, N. ; Lehn, J.-M. Angew. Chem. Int. Ed. 2006, 45, 4619–4624. Hot Paper Angewandte |
| Tunable Fluorene-Based Dynamers through Constitutional Dynamic Chemistry Giuseppone, N. ; Fuks, G. ; Lehn, J.-M. Chem. Eur. J. 2006, 12, 1723–1735. |
| Protonic and Temperature Modulation of Constituent Expression by Component Selection in a Dynamic Combinatorial Library of Imines Giuseppone, N. ; Lehn, J.-M. Chem. Eur. J. 2006, 12, 1715–1722. |
| Transiminations under Scandium Triflate Catalysis. Independent and Constitutionally Coupled Reactions Giuseppone, N. ; Schmitt, J.-L. ; Lehn, J.-M. J. Am. Chem. Soc. 2005, 127, 5528–5539. |
| Generation of Dynamic Constitutional Diversity and Driven Evolution in Helical Molecular Strands under Lewis Acid Catalyzed Component Exchange Giuseppone, N. ; Schmitt, J.-L. ; Lehn, J.-M. Angew. Chem. Int. Ed. 2004, 43, 4902-4906. Front Cover Angewandte |
| Dynamic Constitutional Self-Sensing in a Zn(II) / Poly-Iminofluorenes Systems Giuseppone, N. ; Lehn, J.-M. J. Am. Chem. Soc. 2004, 126, 11448–11449. |