Selected Scientific Publications



2022 - 2021

A light-driven molecular whirligig.
Gao, C., Vargas Jentzsch, A., Moulin, E., Giuseppone. N.
J. Am. Chem. Soc. 2022, 144, 22, 9845–9852, DOI: 10.1021/jacs.2c02547

 

Light-driven molecular motors boost the selective transport of alkali ions through phospholipid bilayers.
Wang, W.-Z., Huang, L.-B., Zheng, S.-P. Moulin, E., Gavat, O., Barboiu, M., Giuseppone, N.
J. Am. Chem. Soc., 2021, 143, 15653-15660.

 

Extraction of Macroscopic Mechanical Work from Stimuli-Responsive Materials.
Perrot, A., Moulin, E., Giuseppone, N.
Trends in Chemistry, 2021, 11, 926-942.

 

Supramolecular Polymerization of Triarylamine-based Macrocycles into Electroactive Nanotubes.
Picini, F., Schneider, S., Gavat, O., Vargas Jentzsch, A., Tan, J., Maaloum, M., Strub, J.-M., Tokunaga, S., Lehn, J.-M., Moulin, E., Giuseppone, N.
J. Am. Chem. Soc. 2021, 143, 6498-6504.

 

Optoregulated force application to cellular receptors using molecular motors.
Zheng, Y., Han, M.K.L., Zhao, R., Blass, J., Zhang, J., Zhou, D.W., Colard-Itté, J.-R., Dattler, D., Hoth, M., Garcia, A.J., Bennewitz, R., Giuseppone, N., del Campo, A.
Nature Comm. 2021, 12, 3580.

 

Template-Directed Synthesis of Redox-Active [c3]Daisy Chain Rotaxanes.
Carmona-Vargas, C., Giuseppone N.
Chem 2021, 7, 11-13.

 

Spatially Addressed Supramolecular Nanowires: A Full Structural Characterization by GIWAXS.
Galerne, M., Heinrich, B., Hemmerle, A., Fontaine, P., Giuseppone, N., Kékicheff, P.,
ACS Appl. Polym. Mat. 2021, 3, 661-670.

 

Modulation of the Molecular Structure of Tri-aryl Amine Fibrils in Hybrid Poly[vinyl chloride] Gel/Organogel Systems
Talebpour, P., Heinrich, B., Gavat, O., Carvalho, A., Moulin, E., Giuseppone, N., Guenet, J.-M., 
Macromolecules 2021, 54, 80104-8111.

 

Design of Stimuli-Responsive Dynamic Covalent Delivery Systems for Volatile Compounds (Part 2): Fragrance-Releasing Cleavable Surfactants in Functional Perfumery Applications.
Tchakalova, V., Lutz, E., Lemboley, S., Moulin, E., Benczédi, D., Giuseppone, N., Herrmann, A.,
Chem. Eur. J. 2021, 27, 13468-13476.

 

Design of Stimuli-Responsive Dynamic Covalent Delivery Systems for Volatile Compounds (Part 1): Controlled Hydrolysis of Micellar Amphiphilic Imines in Water.
Lutz, E., Moulin, E., Tchakalova, V., Benczédi, D., Herrmann, A., Giuseppone, N.,
Chem. Eur. J. 2021, 27, 13457-13467.

 

 


2020 - 2018

 

From molecular machines to stimuli-responsive materials
Moulin, E. ; Faour, L. ; Carmona-Vargas, C. ; Giuseppone, N.
Adv. Mater. 2020, DOI: 10.1002/adma.201906036
Video Abstract

Design of Collective Motions from Synthetic Molecular Switches, Rotors, and Motors
Dattler, D. ; Fuks, G. ; Heiser, J. ; Moulin, E. ; Perrot, A. ; Yao, X. ; Giuseppone, N.
Chem. Rev. 2020, 120, 310-443.
Front Cover

Self-Assembly of Supramolecular Polymers of N-Centered Triarylamine Trisamides in the Light of Circular Dichroism: Reaching Consensus between Electrons and Nuclei
Koenis, M. A. J. ; Osypenko, A. ; Fuks, G. ; Giuseppone, N. ; Nicu, V. P. ; Visscher, L. ; Buma, W. J.
J. Am. Chem. Soc. 2020, 142, 1020-1028.

Triarylamine-based Supramolecular Polymers: Structures, Dynamics, Functions
Moulin, E.; Armao IV, J. J.; Giuseppone, N.
Acc. Chem. Res.
2019, 52, 975-983.
Front Cover

Covalently trapped triarylamine-based supramolecular polymers
Liang, T. ; Collin, D. ; Galerne, M. ; Fuks, G. ; Vargas Jentzsch, A. ; Maaloum, M. ; Carvalho, A. ; Giuseppone, N. ; Moulin, E.
Chem. Eur. J.
2019, 25, 14341-14348.

Temperature Control of Sequential Nucleation‐Growth Mechanisms in Hierarchical Supramolecular Polymers
Osypenko, A. ; Moulin, E. ; Gavat, O. ; Fuks, G. ; Maaloum, M. ; Koenis, M. A. J. ; Buma, W. J. ; Giuseppone, N.
Chem. Eur. J.
2019, 25, 13008-13016.
Hot Paper

Unsymmetric bistable [c2]daisy chain rotaxanes which combine two types of electroactive stoppers
Wolf, A.; Cid, J.-J.; Moulin, E.; Niess, F.; Du, G.; Goujon, A.; Busseron, E.; Ruff, A.; Ludwigs, S.; Giuseppone, N.
Eur. J. Org. Chem.
2019, 3421-3432.
Invited contribution for the special isse "50 years of rotaxanes" edited by J.-P. Sauvage.
Very Important Paper. Feature Cover.

Mechanical behaviour of contractile gels based on light-driven molecular motors
Colard-Itté, J.-R.; Li, Q.; Collin, D.; Mariani, G.; Fuks, G.; Moulin, E.; Buhler, E.; Giuseppone, N.
Nanoscale
2019, 11, 5197-5202.
[c2]daisy chain rotaxanes as molecular muscles
Goujon, A.; Moulin, E.; Fuks, G.; Giuseppone, N.
CCS Chemistry 2019, 1, 83-96.
Supramolecular Electropolymerization
Ellis, T. K.; Galerne, M.; Armao IV, J. J.; Osypenko, A.; Martel, D.; Maaloum, M.; Fuks, G.; Gavat, O.; Moulin, E.; Giuseppone, N.
Angew. Chem. Int. Ed.
2018, 57, 15749-15753.
Hot Paper
3D supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules
Gavat, O.; Nguyet Trinh, T. M.; Moulin, E.; Ellis, T.; Maaloum, M.; Buhler, E.; Fleith, G.; Nierengarten, J.-F.;  Giuseppone, N.
Chem. Commun.
2018, 54, 7657-7660.
Autopoietic Behavior of Dynamic Covalent Amphiphiles
Nguyen, R. ; Jouault, N. ; Zanirati, S. ; Rawiso, M. ; Allouche, L. ; Buhler, E. ; Giuseppone, N.
Chem. Eur. J.
2018, 24, 17125-17137.

2017 - 2015

Dual-light control of nanomachines that integrate motor and modulator subunits
Foy, J. T. ; Li, Q. ; Goujon, A. ; Colard-Itté, J.-R. ; Fuks, G. ; Moulin, E. ; Schiffmann, O. ; Dattler, D. ; Funeriu, D. P. ; Giuseppone, N.
Nature Nanotech. 2017, 12, 540-545.
Highlighted in Nature Nanotech. 2017, 12, 504-506.

Bistable [c2] Daisy Chain Rotaxanes as Reversible Muscle-like Actuators in Mechanically Active Gels
Goujon, A. ; Lang, T. ; Mariani, G. ; Moulin, E. ; Fuks, G. ; Raya, J. ; Buhler, E. ; Giuseppone, N.
J. Am. Chem. Soc. 2017, 139, 14825-14828.

Controlled Sol-gel Transitions by Actuating Molecular Machine based Supramolecular Polymers
Goujon, A. ; Mariani, G. ; Lang, T. ; Moulin, E. ; Rawiso, M. ; Buhler, E. ; Giuseppone, N.
J. Am. Chem. Soc. 2017, 139, 4923-4928.
Highlighted in J. Am. Chem. Soc. 2017, 139, 4969-4970.

Integration of molecular machines into supramolecular materials: actuation between equilibrium polymers and crystal-like gels
Mariani, G. ; Goujon, A. ; Moulin, E. ; Rawiso, M. ; Buhler, E. ; Giuseppone, N.
Nanoscale 2017, 9, 18456-18466.

Columnar Self-Assemblies of Triarylamines as Scaffolds for Artificial Biomimetic Channels for Ion and for Water Transport
Schneider, S. ; Licsandru, E.-D. ; Kocsis, I. ; Gilles, A. ; Dumitru, F. ; Moulin, E. ; Tan, J. ; Lehn, J.-M. ; Giuseppone, N. ; Barboiu, M.
J. Am. Chem. Soc. 2017, 139, 3721–3727.

Anisotropic Self-Assembly of Supramolecular Polymers and Plasmonic Nanoparticles at the Liquid–Liquid Interface
Armao IV, J. J. ; Nyrkova, I. ; Fuks, G. ; Osypenko, A. ; Maaloum, M. ; Moulin, E. ; Arenal, R. ; Gavat, O. ; Semenov, A. ; Giuseppone, N.
J. Am. Chem. Soc. 2017, 139, 2345–2350.

Existence of Two‐Dimensional Physical Gels even at Zero Surface Pressure at the Air/Water Interface: Rheology of Self‐Assembled Domains of Small Molecules
Veschgini, M. ; Habe, T. ; Mielke, S. ; Inoue, S. ; Liu, X. ; Krafft, M. P. ; Tanaka, M.
Angew. Chem. Int. Ed. 2017, 56, 12603–12607.

Thermodynamic Selection of Supramolecular Nanomaterials from Dynamic Peptide Librairies
Rete, C.-V.; Giuseppone, N.
Chem. 2016, 1, 826-829.

Design of Highly Stable Echogenic Microbubbles through Controlled Assembly of Their Hydrophobin Shell
Gazzera, L. ; Milani, R. ; Pirrie, L. ; Schmutz, M. ; Blanck, C. ; Resnati, G. ; Metrangolo, P. ; Krafft, M. P.
Angew. Chem. Int. Ed. 2016, 55, 10263-10267.

Long-Range Energy Transport via Plasmonic Propagation in a Supramolecular Organic Waveguide
Armao, J. J. ; Rabu, P. ; Moulin, E. ; Giuseppone, N.
Nano Lett. 2016, 16, 2800-2805.

Supramolecular Organic Nanowires as Plasmonic Interconnects
Armao, J. J. ; Domoto, Y. ; Umehara, T. ;  Maaloum, M. ; Contal, C.; Fuks, G. ; Moulin, E. ;  Decher, G. ; Javahiraly, N. ; Giuseppone, N.
ACS Nano 2016, 10, 2082-2090.

Self-Assembly of Supramolecular Triarylamine Nanowires in Mesoporous Silica and Biocompatible Electrodes Thereof
Licsandru, E.-D. ; Schneider, S. ; Tingry, S. ; Ellis, T. ; Moulin, E. ; Maaloum, M. ; Lehn, J.-M. ; Barboiu, M. ; Giuseppone, N.
Nanoscale 2016, 8, 5605-5611.

Hierarchical Self-Assembly of Supramolecular Muscle-like Fibers
Goujon, A. ; Du, G. ; Moulin, E. ; Fuks, G. ; Maaloum, M. ; Buhler, E. ; Giuseppone, N.
Angew. Chem. Int. Ed. 2016, 55, 703-707.
Hot Paper Angewandte

Light Scattering Strategy for the Investigation of Time-evolving Heterogeneous Supramolecular Self-Assemblies
Jouault, N. ; Moulin, E. ; Giuseppone, N. ; Buhler, E.
Phys. Rev. Lett. 2015, 115, 085501.

Hydrogen-Bonded Multifunctional Supramolecular Copolymers in Water
Xiang, Y. ; Moulin, E. ; Buhler, E. ; Maaloum, M. ; Fuks, G. ; Giuseppone, N.
Langmuir 2015, 31, 7738-7748.

Recruitment and Immobilization of a Fluorinated Biomarker Across an Interfacial Phospholipid Film using a Fluorocarbon Gas
Yang, G. ; O'Duill, M. ; Gouverneur, V. ; Krafft, M. P.
Angew. Chem. Int. Ed., 2015, 54, 8402-8406.
Very Important Paper (VIP) Angewandte

The evolution of spatial ordering of oil drops fast spreading on a water surface
Yamamoto, D. ; Nakajima, C. ; Shioi, A. ; Krafft, M.-P. ; Yoshikawa, K.
Nature Commun., 2015, 6, 7189.

Macroscopic contraction of a gel induced by the integrated motion of light-driven molecular motors
Li, Q. ; Fuks, G. ; Moulin, E. ; Maaloum, M. ; Rawiso, M. ; Kulic, I. ; Foy, J. T. ; Giuseppone, N.
Nature Nanotech., 2015, 10, 161-165.

Light-Controlled Morphologies of Self-Assembled Triarylamine-Fullerene Conjugates
Busseron, E. ; Cid, J.-J. ; Wolf, A. ; Du, G. ; Moulin, E. ; Fuks, G. ; Maaloum, M. ; Polavarapu, P. ; Ruff, A. ; Saur, A.-K. ; Ludwigs, S. ; Giuseppone, N.
ACS Nano, 2015, 9, 2760-2772.

pH and light-controlled self-assembly of bistable [c2] daisy chain rotaxanes
Wolf, A. ; Moulin, E. ; Cid, J.-J. ; Goujon, A. ; Du, G. ; Busseron, E. ; Fuks, G. ; Giuseppone, N.
Chem. Commun., 2015, 51, 4212-4215.

Control over Nanostructures and Associated Mesomorphic Properties of Doped Self-Assembled Triarylamine Liquid Crystals
Domoto, Y. ; Busseron, E. ; Maaloum, M. ; Moulin, E. ; Giuseppone, N.
Chem. Eur. J., 2015, 21, 1938-1948.
Cover Chem. Eur. J.

Self-assembled Supramolecular Materials in Organic Electronics
Moulin, E. ; Busseron, E. ; Giuseppone, N.
RSC Smart Materials Series
2015, N°12, p1-52 (edited by Nobert Koch)

2014 - 2012

Supramolecular Self-Assembly and Radical Kinetics in Conducting Self-Replicating Nanowires
Nyrkova, I. ; Moulin, E. ; Armao, J.J. ; Maaloum, M. ; Heinrich, B. ; Rawiso, M. ; Niess, F. ; Cid, J.-J.; Jouault, N. ; Buhler, E. ; Semenov, A. N. ; Giuseppone, N.
ACS Nano 2014, 8, 10111-10124.

Atomic force microscopy study of DNA flexibility on short length scales: smooth bending versus kinking
Mazur, A. K. ; Maaloum, M.
Nucl. Acids Res.
2014, 42, 14006-14012.

Healable supramolecular polymers as organic metals
Armao, J.J. ; Maaloum, M. ; Ellis, T. ; Fuks, G. ; Rawiso, M. ; Moulin, E. ; Giuseppone, N.
J. Am. Chem. Soc. 2014, 136, 11382–11388.

Reversible Native Chemical Ligation: a Facile Access to Dynamic Covalent Peptides
Ruff, Y. ; Garavini, V. ; Giuseppone, N.
J. Am. Chem. Soc. 2014, 136, 6333–6339
Highighted in: Nature SciBX, 2014, 7

DNA flexibility on short length scales probed by atomic force microscopy
Mazur, A. K. ; Maaloum, M.
Phys. Rev. Lett. 2014, 112, 068104.
Chiral mechanical bonds: A move in the right direction
Moulin, E. ; Giuseppone, N.
Nature Nanotech.
2014, 9, 331–332
Core–shell inversion by pH modulation in dynamic covalent micelles
Nguyen, R. ; Jouault, N. ; Zanirati, S. ; Rawiso, M. ; Allouche, L. ; Fuks, G. ; Buhler, E. ; Giuseppone, N.
Soft Matter 2014, 10, 3926-3937
Experimental and theoretical methods for the analyses of dynamic combinatorial libraries
Misuraca, M.-C. ; Moulin, E. ; Ruff, Y. ; Giuseppone, N.
New J. Chem. 2014, 38, 3336-3349.
Supramolecular self-assemblies as functional nanomaterials
Busseron, E. ; Ruff, Y. ; Moulin, E. ; Giuseppone, N.
Nanoscale 2013, 5, 7098-7140.
Behavior of an Adsorbed Phospholipid Monolayer Submitted to Prolonged Periodical Surface Density Variations
Nguyen, P. N. ; Waton, G. ; Vandamme, T. ; Krafft, M.-P.
Angew. Chem. Int. Ed. 2013, 52, 6404-6408.
Advances in Supramolecular Electronics – From Randomly Self-assembled Nanowires to Addressable Self-organized Interconnects
Moulin, E. ; Cid, J.-J. ; Giuseppone, N.
Adv. Mater. 2013, 25, 477-487.
Muscle-like Supramolecular Polymers - Integrated Motions from Thousands of Molecular Machines
Du, G. ; Moulin, E. ; Jouault, N. ; Buhler, E. ; Giuseppone, N.
Angew. Chem. Int. Ed. 2012, 51, 12504-12508.
Front Cover Angewandte
Highlighted in: Nature Nano. 2013, 8, 9-10.
Light-triggered self-assembly of triarylamine-based nanospheres
Moulin, E. ; Niess, F. ; Fuks, G. ; Jouault, N. ; Buhler, E. ; Giuseppone, N.
Nanoscale
2012, 4, 6748-6751
Light-triggered self-construction of supramolecular organic nanowires as metallic interconnects
Faramarzi, V. ; Niess, F. ; Moulin, E. ; Maaloum, M. ; Dayen, J.-F. ; Beaufrand, J.-B. ; Zanettini, S. ; Doudin, B. ; Giuseppone, N.
Nature Chem.
2012, 4, 485-490.
Toward Self-Constructing Materials : A Systems Chemistry Approach
Giuseppone, N.
Acc. Chem. Res. 2012, 45, 2178-2188.
Dynamic combinatorial chemistry as a tool for the design of functional materials and devices
Moulin, E. ; Cormos, G. ; Giuseppone, N.
Chem. Soc.
Rev. 2012, 41, 1031-1049.
Reactions in Dynamic Assemblies
Moulin, E. ; Giuseppone, N.
Encyclopedia of Supramolecular Chemistry – From molecules to nanomaterials, John Wiley & Sons, Ltd., 2012, 1543-1574.
Dynamic Combinatorial Self-Replicating Systems
Moulin, E. ; Giuseppone, N.
Topics in Current Chemistry, 2012, 322, 87-105.
Hierarchical supramolecular structuring and dynamical properties of water soluble polyethylene glycol–perylene self-assemblies
Jouault, N. ; Xiang, Y. ; Moulin, E. ; Fuks, G. ; Giuseppone, N. ; Buhler, E.
Phys.
Chem. Chem. Phys. 2012, 14, 5718-5728.

2011 - 2004

Catalytic Accordions
Giuseppone, N. ; Lutz, J.-F.
Nature
2011, 473, 40-41
SANS, SAXS, and light scattering investigations of pH-responsive dynamic combinatorial mesophases
Jouault, N. ; Nguyen, R. ; Rawiso, M. ; Giuseppone, N. ; Buhler, E.
Soft Matter
2011, 7, 4787-4800
The Hierarchical Self-Assembly of Charge Nanocarriers : A Highly Cooperative Process Promoted by Visible Light
Moulin, E. ; Niess, F. ; Maaloum, M. ; Buhler, E. ; Nyrkova, I. ; Giuseppone, N.
Angew.
Chem. Int. Ed. 2010, 49, 6974-6978.
Frontispiece Cover Angewandte
Hierarchical Functional Gradients of pH-Responsive Self-Assembled Monolayers using Dynamic Covalent Chemistry on Surfaces
Tauk, L. ; Schröder, A. ; Decher, G. ; Giuseppone, N.
Nature Chem.
2009, 1, 649-656.
Dynablocks : Structural Modulation of Responsive Combinatorial Self-Assemblies at Mesoscale
Nguyen, R. ; Buhler, E. ; Giuseppone, N.
Macromolecules
2009, 42, 5913-5915.
Dynamic Combinatorial Evolution within Self-Replicating Supramolecular Assemblies
Nguyen, R. ; Allouche, L. ; Buhler, E. ; Giuseppone, N.
Angew. Chem. Int. Ed. 2009, 48, 1093-1096.
Hot Paper Angewandte
Electric-Field Triggered Controlled Release of Bioactive Volatiles from Imine-Based Liquid Crystalline Phases
Herrmann, A. ; Giuseppone, N. ; Lehn, J.-M.
Chem. Eur. J. 2009, 15, 117-124.
Self-Duplicating Amplification in a Dynamic Combinatorial Library
Xu, S. ; Giuseppone, N.
J. Am.
Chem. Soc. 2008, 130, 1826-1827.
DOSY NMR Experiments as a Tool for the Analysis of Constitutional and Motional Dynamic Processes : Implementation for the Driven Evolution of Dynamic Combinatorial Libraries of Helical Strands
Giuseppone, N. ; Schmitt, J.-L. ; Allouche, L. ; Lehn, J.-M.
Angew. Chem. Int. E. 2008, 47, 2235-2239.
Driven Evolution of a Constitutional Dynamic Library of Molecular Helices towards the Selective Generation of 2x2 Grid-like Arrays under the Pressure of Metal Ion Coordination
Giuseppone, N. ; Schmitt, J.-L. ; Lehn, J.-M.
J. Am. Chem. Soc. 2006, 128, 16748–16763.
Electric-Field Modulation of Component Exchange in Constitutional Dynamic Liquid Crystals
Giuseppone, N. ; Lehn, J.-M.
Angew. Chem. Int. Ed. 2006, 45, 4619–4624.
Hot Paper Angewandte
Tunable Fluorene-Based Dynamers through Constitutional Dynamic Chemistry
Giuseppone, N. ; Fuks, G. ; Lehn, J.-M.
Chem. Eur. J. 2006, 12, 1723–1735.
Protonic and Temperature Modulation of Constituent Expression by Component Selection in a Dynamic Combinatorial Library of Imines
Giuseppone, N. ; Lehn, J.-M. 
Chem. Eur. J.
2006, 12, 1715–1722.
Transiminations under Scandium Triflate Catalysis. Independent and Constitutionally Coupled Reactions
Giuseppone, N. ; Schmitt, J.-L. ; Lehn, J.-M. 
J. Am.
Chem. Soc. 2005, 127, 5528–5539.
Generation of Dynamic Constitutional Diversity and Driven Evolution in Helical Molecular Strands under Lewis Acid Catalyzed Component Exchange
Giuseppone, N. ; Schmitt, J.-L. ; Lehn, J.-M. 
Angew.
Chem. Int. Ed. 2004, 43, 4902-4906.
Front Cover Angewandte
Dynamic Constitutional Self-Sensing in a Zn(II) / Poly-Iminofluorenes Systems
Giuseppone, N. ; Lehn, J.-M.
J. Am. Chem. Soc. 2004, 126, 11448–11449.